WebA polymer including a self-immolative polymer segment and a thermally-activated trigger moiety is described. The self-immolative polymer segment includes a head end, a tail end, and a plurality of repeating units. The trigger moiety includes a cycloaddition adduct that is covalently coupled to the head end of the self-immolative polymer segment. WebApr 1, 2024 · A promising transient polymer is cyclic poly-(phthalaldehyde) (cPPA), which has a room temperature storage modulus of 1.5−2 GPa 12 and is prepared in a scalable, one-step cationic polymerization ...

Tunable transient and mechanical properties of photodegradable Poly …

WebAug 7, 2013 · A promising transient polymer is cyclic poly-(phthalaldehyde) (cPPA), which has a room temperature storage modulus of 1.5−2 GPa 12 and is prepared in a scalable, … Web2 days ago · O-Phthalaldehyde (CAS 643-79-8), yellow or light yellow crystalline, mainly used in medicine, dyestuff and so on.O-Phthalaldehyde market size is estimated to be worth … crypto asset or cryptoasset

Acid‐catalyzed degradation mechanism of poly(phthalaldehyde): …

WebNov 6, 2024 · Poly(phthalaldehyde) (pPHA) and copolymers with aliphatic aldehydes were investigated as dry-develop, positive-tone photoresist. Exposure of the films loaded with a … Poly(phthalaldehyde), abbreviated as PPA, is a metastable stimuli-responsive polymer first synthesized in 1967. It has garnered significant attention during the past couple of years due to its ease of synthesis and outstanding transient and mechanical properties. for this reason, It has been exploited for a … See more Poly(phthalaldehyde) was first reported in 1967 by Chuji Aso and Sanae Tagami from the department of Organic Synthesis at Kyushu University by an addition homopolymerization reaction of aromatic o-phthalaldehyde (Figure … See more PPA is a metastable polymer known for its ease of synthesis and rapid depolymerization. In addition, its properties can be easily influenced and manipulated upon either functionalizing the phthalaldehyde monomer with different groups, most … See more According to the safety data sheet of PPA, it should not be allowed in contact with the skin or eyes as it may lead to skin, eye, and respiratory irritations or allergic reactions. In addition, as some … See more Since its first inception in 1967, many synthesis techniques have been developed and employed for the polymerization of o-phthalaldehyde. Most notably, living polymerization methods … See more Depending on the polymerization technique applied, two different types of poly(phthalaldehyde) can be acquired, linear and cyclic (see Figure 1). In this section, the … See more Due to its unique stability, chemical properties, and outstanding tunability and reactivity, PPA has been employed in a variety of applications. Photoresist The high solubility and stability of PPA in organic solvents … See more WebAug 12, 2024 · 1. Introduction. Transient devices are an emerging field of research, where polymer films with a limited lifetime are formed through use of degradable materials [].Poly(phthalaldehyde) (PPHA) is of interest for transient devices because it is metastable at room temperature and its decomposition can be triggered by external stimuli [, , , , ]. durafold hot box